This is an exciting project! I'm thinking, now, how to use these pictures to complement PlaymoDB, and vice versa.
For body-parts and accessories, it would be impossible to find all the part numbers for them (but I do have some!) so I don't think I'll even try to match them up with part-numbers. They could be matched with "Who's That Klicky?" results, though.
Part numbers for the majority of the wearables, weapons, tools and flags could be found, I think. As Tim said, he's taking care of shields and horse-gear, and very well too - no need to re-do his work! Your photos tend to be grouped in the same way that I've assigned categories to parts, so that's helpful. Identification of printed parts, in particular, could benefit from some clear photography.
There seems to be lots of new styles and colours of hair that I haven't described properly in the DB. Even the classic spiky male hair has been re-molded, and I'm really not sure what klickies have it. Good clear front/back/side photos would be excellent.
It's especially useful to see parts that are the same shape but SLIGHTLY different colours, next to each other. All the green/dark green/light green/mint green/dusty green/aqua torsos, for example - brown/orange/dark orange/red-brown hair is even worse.
How else can these photos help PlaymoDB, and PlaymoDB help to complete and organize the photos so they're more useful? Let's brainstorm.